Fastener Surface Treatments and Corrosion Protection — Zinc Plating (ISO 4042), Zinc Flake (ISO 10683), Hot-Dip Galvanising (ISO 10684), Zn-Ni, Phosphate, Black Oxide and Stainless

Selection guide compiled by cBallast. 1-page PDF; the full content is on this page.
Compiled by
cBallast
Subject
Coated and plated threaded fasteners
Document type
Selection guide
Reference
ISO 4042 / ISO 10683 / ISO 10684 / ISO 9227 / ISO 12944
Issued
2026-09-15
Pages
1
Format
Web page and PDF

Comparison of the finishes used on standard fasteners: zinc electroplating with Cr(III) passivation (blue/clear, yellow, black, with sealer), zinc-nickel, zinc flake (Geomet, Delta-Protekt, Dacromet-type), hot-dip galvanising, zinc and manganese phosphate, black oxide and stainless steel — with typical coating thickness, neutral-salt-spray life to white and red rust (ISO 9227), suitability per property class (hydrogen embrittlement), thread-tolerance effects (6g/6H vs 6az/6ax oversize nuts), galvanic compatibility, and which finish to specify for corrosivity categories C1–C5 of ISO 12944.

Fastener Surface Treatments and Corrosion Protection — Zinc Plating (ISO 4042), Zinc Flake (ISO 10683), Hot-Dip Galvanising (ISO 10684), Zn-Ni, Phosphate, Black Oxide and Stainless

Bufab Catalogue data and standard-part designations in this guide follow the cBallast C-Parts range, supplied through Bufab (Värnamo, Sweden). Values are nominal reference data; confirm against the controlling standard revision before procurement.

A fastener finish does three jobs: it delays corrosion of the steel underneath, it sets the friction (and therefore the torque-to-preload relationship) of the joint, and it must not damage the fastener in the process — the hydrogen absorbed during acid pickling and electroplating can embrittle steel above about 320 HV (property class 10.9 and up). The right choice depends on the service environment (ISO 12944 corrosivity category), the property class, the mating parts and the tolerance budget of the thread. The table gives typical values; the standards referenced fix the requirements.

Finish (common codes)Typical thicknessNSS to white / red rust (ISO 9227, typical)Property class limitThread effectNotes
Plain (untreated, may be lightly oiled)—hoursanynoneIndoor dry service or where the joint is painted after assembly
Zinc electroplated, Cr(III) clear/blue passivated (ZPL, Fe/Zn 5–8 µm, ISO 4042)5 – 8 µm24–72 h / 96–150 h≤ 10.9 with baking; avoid 12.96g bolt before plating; nut 6HStandard industrial finish; decorative; C2–C3 indoors
Zinc electroplated, Cr(III) thick-film / yellow passivated (YZPL)8 – 12 µm96–150 h / 200–300 h≤ 10.9 with bakingas aboveHigher salt-spray life than blue; colour is not a guarantee of Cr(VI)-free unless stated
Zinc electroplated + sealer / top coat8 – 12 µm + seal150–250 h / 300–500 h≤ 10.9 with bakingas aboveSealer also fixes friction (µ 0.12–0.14 typical)
Zinc-nickel (Zn-Ni 12–15 % Ni, 8 µm, ISO 19598)8 – 12 µm150–300 h / 720–1000 h≤ 10.9 (low embrittlement risk with control)as aboveAutomotive and off-highway standard; good at 150–200 °C; silver or black
Zinc flake, non-electrolytic (ISO 10683; Geomet 500, Delta-Protekt KL 100, Dacromet-type)8 – 12 µm240–480 h / 600–1000 hall classes incl. 10.9 and 12.9 (no hydrogen)thin — fits 6g/6HDefault for 10.9/12.9 outdoor; friction controlled by top coat (e.g. Geomet 500 A = µ 0.12–0.18 range with lubricant)
Hot-dip galvanised (HDG, ISO 10684; tZn)≥ 40 – 50 µm (≥ 45 µm local typ.)not NSS-rated; 1–2 µm/yr loss in C3, 4–8 in C5≤ 8.8 routinely; 10.9 only with qualified processbolt normal; nut tapped oversize 6AZ/6AXStructural steel, outdoor, marine deck; rough surface; ISO 1461 for the structure
Zinc phosphate + oil (PHM)2 – 8 µm24–72 h (oil-dependent)allnoneCorrosion protection in transit and storage; paint base; good lubricity
Manganese phosphate5 – 15 µm48–96 h with oilallnoneWear-resistant, anti-galling for sliding parts and set screws
Black oxide (BLACK OXIDE) + oil< 1 µm< 24 hall (no hydrogen)noneCosmetic / indoor; socket screws 12.9 are usually black oxide
Nickel plated5 – 10 µm48–150 h≤ 10.9 with bakingas platingDecorative, brass and copper parts
Stainless A2 (EN 1.4301/1.4307)n/ano red rust; tea staining possible in C4+A2-70 ≤ M20noneAtmospheric, food, water; not for chloride-rich or splash zones
Stainless A4 (EN 1.4401/1.4404)n/aresists chlorides; pitting possible in stagnant seawaterA4-70 / A4-80 ≤ M20noneMarine, chemical, coastal; isolate from carbon steel and aluminium

Matching the finish to the corrosivity category (ISO 12944-2)

Hydrogen embrittlement and baking

Electroplating and acid pickling charge steel with hydrogen. In fasteners harder than about 320 HV (class 10.9 and above, spring steel, case-hardened screws) this can cause delayed brittle fracture under static load, days after assembly. ISO 4042 requires the plater to assess the risk and, where needed, bake the parts (typically 190–230 °C for 4–24 h, started within 4 h of plating) and to run process verification per ISO 15330 (sustained-load test). Zinc flake and mechanical plating avoid the problem because no hydrogen is generated — that is why 10.9 and 12.9 outdoor fasteners are normally zinc flake. Hot-dip galvanising at ~450 °C can temper 10.9 steel; ISO 10684 allows it only with process controls and excludes 12.9.

Thread tolerances and coating thickness

A coating adds to the pitch diameter four times its thickness (it sits on both flanks). Electroplated bolts are therefore made to 6g and plated to a thickness that keeps them inside 6h; nuts stay 6H. Hot-dip zinc is too thick for that: ISO 10684 keeps the bolt thread normal (6g before dip) and requires the nut to be tapped oversize after galvanising — tolerance class 6AZ (nut over-tapped by 0.3–0.5 mm on the pitch diameter, standard) or 6AX (larger oversize for plating the nut too). An HDG bolt with an ordinary 6H nut will seize; an oversize nut on an ordinary bolt loses about 15 % load capacity and must be class-checked.

Friction and torque

The finish sets the friction coefficient the torque table assumes. Plain and black-oxide steel with light oil: µ ≈ 0.14–0.20; zinc plated (dry): 0.12–0.18; zinc flake with integrated lubricant (Geomet 500 A/B, Delta-Protekt KL 100 with VH 301 top coat): 0.09–0.15 and tightly controlled; hot-dip galvanised: 0.16–0.25 and scattered — HDG joints are normally tightened by turn-of-nut rather than torque. Zn-Ni without sealer runs high (0.20+). Always take the torque value from a table for the actual finish and lubrication state; the same bolt with a different finish can need 40 % more or less torque for the same preload.

Galvanic pairs to avoid

Specifying the finish on the order

Use the standard's designation so the plater and the buyer mean the same thing. Examples: "ISO 4042 – Fe//Zn8//An//T0" = 8 µm zinc, trivalent clear passivation, no top coat; "Fe//Zn8//Cn//T2" = 8 µm zinc, thick-film/iridescent passivation, sealed; "ISO 10683 – flZn nc 480 h" = zinc flake, no Cr(VI), 480 h neutral salt spray to red rust; "ISO 10684 tZn" = hot-dip galvanised with oversize-tapped nuts. Add the required salt-spray hours, whether the value is to white or red rust, and the friction window (e.g. µ_tot 0.09–0.14) if the joint is torque-controlled.

Browse the C-Parts range · Bufab · Related: fastener standards cross-reference · torque wrench calibration (ISO 6789) · ASTM A193 B7 stud bolts.

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Compiled by cBallast for identification and cross-reference. Part numbers, designations and trademarks belong to their respective manufacturers. Confirm ratings and dimensions against the manufacturer's current documentation and the nameplate of the installed equipment before ordering or installation.